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123315

Sigma-Aldrich

1,4-Butanediol divinyl ether

98%

Synonym(s):

1,4-Bis(vinyloxy)butane, 1,4-Butylene glycol divinyl ether, 1,4-Divinyloxybutane

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About This Item

Linear Formula:
(-CH2CH2OCH=CH2)2
CAS Number:
Molecular Weight:
142.20
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Quality Level

Assay

98%

refractive index

n20/D 1.444 (lit.)

bp

62-64 °C/10 mmHg (lit.)

mp

−8 °C (lit.)

density

0.898 g/mL at 25 °C (lit.)

SMILES string

C=COCCCCOC=C

InChI

1S/C8H14O2/c1-3-9-7-5-6-8-10-4-2/h3-4H,1-2,5-8H2

InChI key

MWZJGRDWJVHRDV-UHFFFAOYSA-N

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This Item
BP1247Y00005251569315
assay

≥98% (HPLC)

assay

-

assay

-

assay

-

form

powder

form

powder

form

-

form

-

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

-

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

solubility

DMSO: 5 mg/mL, clear (warmed)

solubility

-

solubility

-

solubility

-

color

white to beige

color

-

color

-

color

-

General description

1,4-Butanediol divinyl ether is widely used as across-linking agent to synthesize polymeric membranes, copolymer networks, and microspheres. For example, it can be used as a precursor to synthesize electrolyte membranes for fuel cell applications and thermally expandable microspheres.

Application

  • Comparative physicochemical analysis among 1, 4-butanediol diglycidyl ether cross-linked hyaluronic acid dermal fillers: This study explores the properties of hyaluronic acid dermal fillers cross-linked with 1,4-butanediol diglycidyl ether, focusing on their physicochemical characteristics and performance in cosmetic applications (Zerbinati et al., 2021).
  • In-depth characterization of 1, 4-butanediol diglycidyl ether substituted hyaluronic acid hydrogels: An investigation into the properties of hyaluronic acid hydrogels modified with 1,4-butanediol diglycidyl ether, providing insights into their structural and functional enhancements (Zhang et al., 2023).
  • Highly Branched Poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) for High Performance Gene Transfection: Discusses the synthesis and application of a novel branched polymer for gene delivery, highlighting the role of 1,4-butanediol diacrylate in enhancing transfection efficiency (Zeng et al., 2017).
  • Tuning thermal, morphological, and physicochemical properties of thermoplastic polyurethanes (TPUs): This study examines the effects of substituting 1,4-butanediol in the synthesis of TPUs, aiming to improve their mechanical properties and performance (Ernzen et al., 2022).
  • Cyclodehydration of 1, 4-butanediol over Zr-Al Catalysts: Focuses on the catalytic transformation of 1,4-butanediol to tetrahydrofuran, a critical industrial solvent and intermediate, using zirconium-aluminum catalysts (Li & Chen, 2019).

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Flam. Liq. 3 - Skin Sens. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

139.1 °F - closed cup

Flash Point(C)

59.5 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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M Stylianou et al.
Dalton transactions (Cambridge, England : 2003), 46(11), 3688-3699 (2017-03-04)
A new two-electron photosensitizer, H
Galina S Matouzenko et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9608-9618 (2011-08-24)
Two polymorphic modifications 1 and 3 of binuclear compound [{Fe(dpia)(NCS)(2)}(2)(bpe)] and pseudo-polymorphic modification [{Fe(dpia)(NCS)(2)}(2)(bpe)]·2CH(3)OH (2), where dpia = di-(2-picolyl)amine, bpe = 1,2-bis(4-pyridyl)ethene, were synthesized, and their structures, magnetic properties, and Mössbauer spectra were studied. Variable-temperature magnetic susceptibility measurements of three
Elena R Milaeva et al.
Dalton transactions (Cambridge, England : 2003), 42(19), 6817-6828 (2013-03-16)
A series of Zn, Mn, Fe, Co, and Ni complexes ([MX2L], X = Cl, OAc) of the novel di-(2-picolyl)amine ligand L with an antioxidant 2,6-di-tert-butylphenol pendant were synthesized and characterized by elemental analysis, IR, multinuclear NMR spectroscopy, MALDI-TOF mass spectrometry
Yaohui Xu et al.
Materials (Basel, Switzerland), 13(17) (2020-08-23)
Fe3O4@SiO2 nanospheres with a core-shell structure were synthesized and functionalized with bis(2-pyridylmethyl)amine (BPMA). The photoresponses of the as-obtained Fe3O4@SiO2-BPMA for Cr3+, Cd2+, Hg2+ and Pb2+ ions were evaluated through irradiation with a 352 nm ultraviolet lamp, and Fe3O4@SiO2-BPMA exhibited remarkable
H M Dhammika Bandara et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(14), 3932-3941 (2011-03-03)
Photocages have been used to elucidate the biological functions of various small molecules and Ca(2+) ; however, there are very few photocages available for other metal ions. ZinCleav-2 (1-(4,5-dimethoxy-2-nitrophenyl)-N,N,N',N'-tetrakis-pyridin-2-ylmethyl-ethane-1,2-diamine) is a second-generation photocage for Zn(2+) that releases the metal ion

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