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About This Item
Linear Formula:
C6H5NHNHC6H5
CAS Number:
Molecular Weight:
184.24
Beilstein:
639793
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Level
mp
123-126 °C (lit.)
SMILES string
N(Nc1ccccc1)c2ccccc2
InChI
1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H
InChI key
YBQZXXMEJHZYMB-UHFFFAOYSA-N
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General description
Hydrazobenzene has been prepared by the reduction of azobenzene by SmI(2) in THF.
Hydrazobenzene is an intermediate in the hydrogenation of azoxybenzene to aniline.
Application
Reactant involved in:
- Insertion reactions with organometallic tantalum complexes
- Reduction reactions catalyzed by titanium(III) trichloride yielding amines
- Studying the mechanism of hydrazobenzene rearrangement
- Reaction with N-heterocyclic stable silylene
- Synthesis of dimanganese amide hydrazide cluster complexes
- Iron-mediated hydrazine reductions yielding iron arylimide cubanes
Other Notes
Contains varying amounts of azobenzene
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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