137677

2-Bromobenzoic acid

97%

• Synonym(s): o-Bromobenzoic acid
• Linear Formula: BrC₆H₄CO₂H
• CAS Number: 88-65-3
• Molecular Weight: 201.02
• Beilstein: 971266
• EC Number: 201-848-6
• MDL number: MFCD00002402
• UNSPSC Code: 12352100
• PubChem Substance ID: 24848342
• NACRES: NA.22

Properties

• vapor pressure: >1 mmHg ( 20 °C)
• Quality Level: 100
• Assay: 97%
• form: powder
• mp: 147-150 °C (lit.)
• solubility: 95% ethanol: soluble 100 mg/mL, clear, colorless to yellow
• functional group: bromo; carboxylic acid
• SMILES string: OC(=O)c1ccccc1Br
• InChI: 1S/C7H5BrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)
• InChI key: XRXMNWGCKISMOH-UHFFFAOYSA-N

Description

General description

2-Bromobenzoic acid (2-BA) on condensation with aminoquinolines yields phenylquinolylamines. 2-BA is the common building block for synthesis of various nitrogen heterocycles.

Application

2-Bromobenzoic acid was used in the synthesis of new zinc(II) − 2-bromobenzoate complex compounds. It was used as the starting reagent in the synthesis of hemilabile benzimidazolyl phosphine ligands.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H319
• Precautionary Statements: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): >212.0 °F
• Flash Point(C): > 100 °C
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves