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269190

Sigma-Aldrich

Methanesulfonic anhydride

97%

Synonym(s):

Mesyl anhydride, Mesylic anhydride, Methanesulfonyl anhydride, Methylsulfonyl methanesulfonate

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2 ML
CA$223.00

About This Item

Linear Formula:
(CH3SO2)2O
CAS Number:
Molecular Weight:
174.20
Beilstein:
972316
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

CA$223.00


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vapor density

3.3 (vs air)

Quality Level

Assay

97%

form

solid

bp

125 °C/4 mmHg (lit.)

mp

64-67 °C (lit.)

functional group

sulfonic acid

SMILES string

CS(=O)(=O)OS(C)(=O)=O

InChI

1S/C2H6O5S2/c1-8(3,4)7-9(2,5)6/h1-2H3

InChI key

IZDROVVXIHRYMH-UHFFFAOYSA-N

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This Item
308M-1ABD116MABD76
antibody form

diluted ascites fluid

antibody form

diluted ascites fluid

antibody form

affinity isolated antibody

antibody form

purified immunoglobulin

biological source

mouse

biological source

mouse

biological source

rabbit

biological source

mouse

conjugate

unconjugated

conjugate

unconjugated

conjugate

-

conjugate

-

clone

MRQ-10, monoclonal

clone

MRQ-2, monoclonal

clone

polyclonal

clone

9B7, monoclonal

species reactivity

human

species reactivity

human

species reactivity

human

species reactivity

mouse

Gene Information

human ... POU5F1(5460)

Gene Information

human ... POU2F2(5452)

Gene Information

human ... POU5F1(5460)

Gene Information

human ... POU5F1(5460)

General description

Methanesulfonic anhydride is an organic compound that is commonly used as a reagent for the preparation of methyl sulfonates (mesylates). It is also used in the synthesis of methanesulfonamides using various amine precursors. Additionally, the mixture of methanesulfonic anhydride and dimethyl sulfoxide can be used as an oxidizing agent for the oxidation of primary and secondary alcohols to aldehydes and ketones.

Application

Methanesulfonic anhydride can be used as an amine base to synthesize glycosyl mesylates in situ from the corresponding free hemiacetals under mild conditions.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1A

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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