563749
9-Phenanthrylmagnesium bromide
0.5 M in THF
About This Item
Recommended Products
reaction suitability
reaction type: Grignard Reaction
Quality Level
concentration
0.5 M in THF
bp
65 °C (lit.)
density
0.970 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
Br[Mg]c1cc2ccccc2c3ccccc13
InChI
1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key
ACMUZKQPXSHTGB-UHFFFAOYSA-M
Related Categories
1 of 4
This Item | L0551000 | 1362602 | BP501 |
---|---|---|---|
technique(s) HPLC: suitable, gas chromatography (GC): suitable | technique(s) - | technique(s) - | technique(s) - |
format neat | format neat | format neat | format neat |
Quality Level 300 | Quality Level - | Quality Level - | Quality Level - |
grade certified reference material, pharmaceutical secondary standard | grade pharmaceutical primary standard | grade pharmaceutical primary standard | grade pharmaceutical primary standard |
storage temp. 2-8°C | storage temp. - | storage temp. - | storage temp. 2-8°C |
packaging pkg of 500 mg | packaging - | packaging - | packaging - |
General description
Application
- 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.[2]
- (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.[3]
- 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).[4]
Legal Information
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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