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567205

Sigma-Aldrich

Tetramethylthiuram monosulfide

97%

Synonym(s):

UNADS

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About This Item

Linear Formula:
((H3C)2NCS)2S
CAS Number:
Molecular Weight:
208.37
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level

Assay

97%

mp

107-111 °C (lit.)

functional group

amine
dithiocarbamate
thioether

SMILES string

CN(C)C(=S)SC(=S)N(C)C

InChI

1S/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3

InChI key

REQPQFUJGGOFQL-UHFFFAOYSA-N

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1 of 4

This Item
T2420186720791784
assay

97%

assay

97%

assay

≥97.0% (S)

assay

97%

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

107-111 °C (lit.)

mp

156-158 °C (lit.)

mp

69-71 °C (lit.)

mp

169-171 °C (lit.)

functional group

amine

functional group

-

functional group

amine, disulfide

functional group

amine

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

312.8 °F - closed cup

Flash Point(C)

156 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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E Schreiner et al.
Toxicology letters, 25(2), 147-152 (1985-05-01)
The epoxide hydrolase (EH) activity in the liver of adult female Wistar rats significantly increased 18 h after the administration by gavage of tetramethyl thiuramdisulfide (TMTD, 1 mmol/kg) or tetramethyl thiurammonosulfide (TMTM, 2 mmol/kg). No increase was observed 5 h
Allergic contact dermatitis of the eyelids from rubber chemicals.
J C Cabrita et al.
Contact dermatitis, 24(2), 145-146 (1991-02-01)
Toxicity studies on tetramethylthiuram monosulfide.
O T Alanis et al.
Environmental research, 28(1), 199-211 (1982-06-01)
A Rannug et al.
Chemico-biological interactions, 49(3), 329-340 (1984-05-01)
In recent years data have accumulated regarding genotoxic properties of dithiocarbamic acid derivatives. The results from the present work indicate that the mutagenicity of these compounds depends on an indirect effect via oxygen radicals. Mutagenicity of tetramethylthiuram disulfide ( TMTD
Contact allergy to Nobecutan.
B Pock-Steen
Contact dermatitis, 18(1), 52-53 (1988-01-01)

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