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About This Item
Empirical Formula (Hill Notation):
C52H77Cl2N2PRu
CAS Number:
Molecular Weight:
933.13
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
form
solid
mp
176-181 °C
storage temp.
2-8°C
SMILES string
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C
InChI
1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
InChI key
VWYWCKUDPDENIJ-UHFFFAOYSA-L
Application
- Bulky NHC ligand results in faster initiation than the Grubbs 2nd Generation Catalyst.
- Has enabled lower catalyst loadings in some applications.
Grubbs Catalyst® M2a SIPr is a second generation Grubb′s catalyst used to catalyze olefin metathesis which low catalyst loading. This is also used in synthesizing variety of highly active second generation fast-initiation Hoveyda type ruthenium catalysts.
Other Notes
Legal Information
Product of Umicore
Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG
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