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794481

Sigma-Aldrich

Ritter Pentafluoroiodoethane-DMSO Reagent

95% (NMR)

Synonym(s):

2DMSO-CF3CF2I

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125 MG
₩486,490

About This Item

Empirical Formula (Hill Notation):
C6H12F5IO2S2
Molecular Weight:
402.18
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

₩486,490


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Quality Level

Assay

95% (NMR)

form

liquid

reaction suitability

reaction type: C-C Bond Formation

refractive index

n/D 1.432

density

1.561 at 25 °C

functional group

fluoro
iodo
sulfoxide

shipped in

dry ice

storage temp.

2-8°C

SMILES string

FC(F)(F)C(F)(F)I.CS(C)=O.CS(C)=O

Application

Product is a more convenient, liquified version of pentafluoroiodoethane, which can be utilized in photocatalytic and electrophilic pentafluoroethylation of olefins and heteroatoms respectively.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

215.0 °F

Flash Point(C)

101.67 °C


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    Andrea Clavijo McCormick et al.
    Plant, cell & environment, 37(8), 1909-1923 (2014-01-30)
    After herbivory, plants release volatile organic compounds from damaged foliage as well as from nearby undamaged leaves that attract herbivore enemies. Little is known about what controls the volatile emission differences between damaged and undamaged tissues and how these affect
    Gary Loake et al.
    Current opinion in plant biology, 10(5), 466-472 (2007-10-02)
    Salicylic acid (SA) is synthesised by plants in response to challenge by a diverse range of phytopathogens and is essential to the establishment of both local and systemic-acquired resistance (SAR). SA application induces accumulation of pathogenesis-related (PR) proteins. Mutations leading
    Caroline Gutjahr et al.
    Molecular plant-microbe interactions : MPMI, 22(7), 763-772 (2009-06-16)
    Work on the interaction of aerial plant parts with pathogens has identified the signaling molecules jasmonic acid (JA) and salicylic acid (SA) as important players in induced defense of the plant against invading organisms. Much less is known about the
    Jyoti Shah
    Current opinion in plant biology, 6(4), 365-371 (2003-07-23)
    Salicylic acid is an important signal molecule in plant defense. In the past two years, significant progress has been made in understanding the mechanism of salicylic-acid biosynthesis and signaling in plants. A pathway similar to that found in some bacteria
    Jon Lucas Boatwright et al.
    Molecular plant pathology, 14(6), 623-634 (2013-04-30)
    Salicylic acid (SA) acts as a signalling molecule in plant defence against biotrophic and hemibiotrophic phytopathogens. The biosynthesis of SA on pathogen detection is essential for local and systemic acquired resistance, as well as the accumulation of pathogenesis-related (PR) proteins.

    Protocols

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