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237523

Sigma-Aldrich

Palladium on barium carbonate

greener alternative

reduced, extent of labeling: 5 wt. % loading

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About This Item

Linear Formula:
Pd
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.23
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Quality Level

form

solid

reaction suitability

reagent type: catalyst
core: palladium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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extent of labeling

5 wt. % loading

greener alternative category

SMILES string

[Pd++].[Ba++].[O-]C([O-])=O.[O-]C([O-])=O

InChI

1S/2CH2O3.Ba.Pd/c2*2-1(3)4;;/h2*(H2,2,3,4);;/q;;2*+2/p-4

InChI key

NFXIBAPFNPIUGD-UHFFFAOYSA-J

Application

Palladium on barium carbonate (5% Pd/BaCO3) is a palladium catalyst that can be used in the cross-coupling reaction of arenediazonium salts with boronic acid at low catalytic loading. It can also be used as a catalyst in the diastereoselective hydrogenations of the imine for the synthesis of chiral trifluoromethyl benzylamines.

Other Notes

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

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Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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