146498
Trimethyltin chloride
동의어(들):
Chlorotrimethylstannane
로그인조직 및 계약 가격 보기
크기 선택
크기 선택
보기 변경
About This Item
Linear Formula:
(CH3)3SnCl
CAS Number:
Molecular Weight:
199.27
Beilstein:
3535111
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
양식
crystals
Quality Level
mp
37-39 °C (lit.)
SMILES string
C[Sn](C)(C)Cl
InChI
1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1
InChI key
KWTSZCJMWHGPOS-UHFFFAOYSA-M
유사한 제품을 찾으십니까? 방문 제품 비교 안내
관련 카테고리
일반 설명
Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.
애플리케이션
Trimethyltin chloride can be used as a precursor to synthesize trimethyltin hydride, cyanide, methoxide, azide, and lithium compounds.
It can also be used as a reagent to prepare:
Me3SnCl can also be used as a Lewis acid catalyst in asymmetric allylic alkylation reactions.
It can also be used as a reagent to prepare:
- Organotrimethyltin derivatives by reacting with organocopper compounds via transmetalation reaction.
- Acetophenone by palladium-catalyzed coupling reaction with benzoyl chloride.
- Optically active propargyl trimethylstannane by treating with chiral allenyltitanium.
- Trimethylstannyl nucleophiles, which are applicable in the formation of Sn-C bonds via SN2 reactions, SRN1 reactions, and halogen-metal exchanges.
- Carbocycles by reacting with unactivated dienes or trienes via radical-mediated carbocyclization reaction in the presence of NaBH3CN and a catalytic amount of AIBN.
Me3SnCl can also be used as a Lewis acid catalyst in asymmetric allylic alkylation reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
Flash Point (°F)
206.6 °F - closed cup
Flash Point (°C)
97 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.