187054

4-Bromobenzyl alcohol

99%

• 동의어(들): (4-Bromophenyl)methanol, (p-Bromophenyl)methanol, 1-(p-Bromophenyl)methanol, 1-Bromo-4-(hydroxymethyl)benzene, 4-Hydroxymethyl-1-bromobenzene, p-Bromobenzyl alcohol
• Linear Formula: BrC₆H₄CH₂OH
• CAS Number: 873-75-6
• Molecular Weight: 187.03
• Beilstein: 1931620
• EC Number: 212-851-7
• MDL number: MFCD00004650
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24851248
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 99%
• 양식: solid
• mp: 75-77 °C (lit.)
• solubility: dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow
• 작용기: bromo; hydroxyl
• SMILES string: OCc1ccc(Br)cc1
• InChI: 1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
• InChI key: VEDDBHYQWFOITD-UHFFFAOYSA-N
• 유전자 정보: human ... ALOX12(239), ALOX15(246)

설명

일반 설명

4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.

애플리케이션

4-Bromobenzyl alcohol was used in the synthesis of:

• hydroxyl end functionalized, substituted polyfluorene
• amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)

안전성 정보

• 유해 및 위험 성명서: H412
• 예방조치 성명서: P273 - P501
• Hazard Classifications: Aquatic Chronic 3
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)