Name: TEMPO
Brand: ALDRICH

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About This Item

실험식(Hill 표기법):

C₉H₁₈NO

CAS Number:

2564-83-2

Molecular Weight:

156.25

Beilstein:

1422418

EC Number:

219-888-8

MDL number:

MFCD00009599

UNSPSC 코드:

12352119

PubChem Substance ID:

24852819

NACRES:

NA.22

기술 서비스

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도움 문의

Quality Level

200

분석

98%

양식

solid

반응 적합성

reagent type: oxidant

환경친화적 대안 제품 특성

Catalysis
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36-38 °C (lit.)

환경친화적 대안 카테고리

Aligned,

저장 온도

2-8°C

SMILES string

CC1(C)CCCC(C)(C)N1[O]

InChI

1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3

InChI key

QYTDEUPAUMOIOP-UHFFFAOYSA-N

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일반 설명

TEMPO (2,2,6,6-Tetramethylpiperidin-1-oxyl) is a stable free radical commonly used as an oxidizing agent in organic synthesis. Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.

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애플리케이션

TEMPO can be used:

As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air