257885

Trimethylsilyl cyclopentadiene, mixture of isomers

• 동의어(들): NSC 176274
• 실험식(Hill 표기법): C₈H₁₄Si
• CAS Number: 3559-74-8
• Molecular Weight: 138.28
• MDL number: MFCD00010666
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24855613
• NACRES: NA.22

속성

• 양식: liquid
• Quality Level: 200
• refractive index: n20/D 1.471 (lit.)
• bp: 138-140 °C (lit.)
• density: 0.833 g/mL at 25 °C (lit.)
• 저장 온도: −20°C
• SMILES string: C[Si](C)(C)C1C=CC=C1
• InChI: 1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
• InChI key: VMFHCJPMKUTMMQ-UHFFFAOYSA-N

설명

일반 설명

Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.

애플리케이션

Reactant involved in:

• Diels-Alder reactions
• Synthesis of ring-functionalized molybdenocene complexes
• Allyl isomerization
• Aromatization of C5 rings
• Synthesis of N-hydroxyindoles via nucleophilic addition

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H226,H315,H319,H335
• 예방조치 성명서: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 84.2 °F - closed cup
• Flash Point (°C): 29 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter