290998

Pentylmagnesium bromide solution

2.0 M in diethyl ether

• 동의어(들): 1-Pentylmagnesium bromide, n-Pentylmagnesium bromide, Amylmagnesium bromide, Bromopentylmagnesium
• Linear Formula: C₅H₁₁MgBr
• CAS Number: 693-25-4
• Molecular Weight: 175.35
• MDL number: MFCD00000045
• UNSPSC 코드: 12352001
• PubChem Substance ID: 24857502
• NACRES: NA.22

속성

• Quality Level: 100
• 반응 적합성: reaction type: Grignard Reaction
• 농도: 2.0 M in diethyl ether
• density: 0.947 g/mL at 25 °C
• SMILES string: CCCCC[Mg]Br
• InChI: 1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
• InChI key: ZXWGTPYWPZGZPT-UHFFFAOYSA-M

설명

애플리케이션

Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:

• Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
• Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.

It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H260,H302,H314,H336
• 예방조치 성명서: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• 표적 기관: Central nervous system
• 보충제 위험성: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): -40.0 °F - closed cup
• Flash Point (°C): -40 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter