394408

1-(Bromoacetyl)pyrene

97%

• 동의어(들): 2-Bromo-1-(1-pyrenyl)ethanone
• 실험식(Hill 표기법): C₁₈H₁₁BrO
• CAS Number: 80480-15-5
• Molecular Weight: 323.18
• MDL number: MFCD00191839
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24864593
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: solid
• mp: 129-131 °C (lit.)
• 작용기: bromo; ketone
• SMILES string: BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34
• InChI: 1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2
• InChI key: KAEDEGFCOPIKKM-UHFFFAOYSA-N

설명

일반 설명

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

애플리케이션

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

• As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
• As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
• As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.

It may also be used in the following studies:

• As a photoremovable protecting group for carboxylic acids and amino acids.
• As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
• As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
• As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314,H413
• 예방조치 성명서: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 4 - Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges