Name: 4-Mercaptophenol
Brand: ALDRICH

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About This Item

Linear Formula:

HSC₆H₄OH

CAS Number:

637-89-8

Molecular Weight:

126.18

Beilstein:

2039306

EC Number:

211-307-6

MDL number:

MFCD00004850

UNSPSC 코드:

12352100

PubChem Substance ID:

24879829

NACRES:

NA.22

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Quality Level

100

분석

97%

bp

149-150 °C/25 mmHg (lit.)

mp

33-35 °C (lit.)

SMILES string

Oc1ccc(S)cc1

InChI

1S/C6H6OS/c7-5-1-3-6(8)4-2-5/h1-4,7-8H

InChI key

BXAVKNRWVKUTLY-UHFFFAOYSA-N

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애플리케이션

4-Mercaptophenol (MPH) has been used to study the adsorption of MPH on silver coated polystyrene nanospheres by time-dependent surface-enhanced Raman scattering (SERS) spectroscopy.
4-Mercaptophenol may be used in the preparation of silylated monomer, which was employed for the synthesis of hyperbranched poly(ester-imide). 4-Mercaptophenol (H-4MP) reacts with metal tert-butoxides ([M(OBu^t)₄]) to yield the following Group 4 phenoxy-thiols:

[(HOBu^t)(4MP)₃M(μ-4MP)]₂, where M = Ti, Zr, Hf
[(py)₂M(4MP)], where M = Ti, Zr; py = pyridine
[(py)(4MP)₃Hf(μ-4MP)]₂

4-Mercaptophenol may be used in the synthesis of the following:

poly(ethersulfide)s via silylation followed by polycondensation with 2,6-dichloropyridine or 3,6-dichloropyridazine
2,6-di-tertiarybutyl-4-mercaptophenol via Friedel-Craft′s alkylation with tert-butyl chloride in presence of a lewis acid