640360

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

• 동의어(들): [Rh(cod)(MeCN)₂]BF₄
• 실험식(Hill 표기법): C₁₂H₁₈BF₄N₂Rh
• CAS Number: 32679-02-0
• Molecular Weight: 379.99
• MDL number: MFCD06798085
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24883086
• NACRES: NA.22

속성

• 양식: solid
• Quality Level: 100
• 반응 적합성: core: rhodium; reagent type: catalyst
• SMILES string: [Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
• InChI: 1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
• InChI key: KSMAFOANQHYEJG-SUESZSCISA-N

설명

애플리케이션

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)₂]BF₄ may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.[1]

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves