697575
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate
동의어(들):
JohnPhos Au(MeCN)SbF6
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250 MG
CA$200.00
About This Item
실험식(Hill 표기법):
C22H30AuF6NPSb
CAS Number:
Molecular Weight:
772.17
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
양식
solid
Quality Level
반응 적합성
core: gold
reagent type: catalyst
mp
198-203 °C (D)
SMILES string
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI
1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key
ADQOZROJMVWPRI-UHFFFAOYSA-H
관련 카테고리
1 of 4
이 품목 | 860417 | 84230 | 717436 |
|---|---|---|---|
| assay 99% | assay 99% | assay ≥99.0% (T) | assay 97% |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 177 °C (dec.) (lit.) | mp 140-144 °C (lit.) | mp 139-141 °C, 140-144 °C (lit.) | mp 74-78 °C |
일반 설명
(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate is a phosphine ligated gold(I) complex. It is used as a catalyst in a domino reaction to form C–C, C–N, and C–O bonds due to the ease with which it can activate C=C and C≡C bonds, thus allowing for unique rearrangements or reactions with various nucleophiles. Gold catalysis provides an excellent method to construct complex chemical architectures in a mild manner that would be difficult to achieve using other reaction paradigms.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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