733210

Tetrakis(dimethylsulfoxide)dichlororuthenium(II)

96%

• 동의어(들): Dichlorotetrakis(dimethyl sulfoxide)ruthenium
• 실험식(Hill 표기법): C₈H₂₄Cl₂O₄RuS₄
• CAS Number: 89395-66-4
• Molecular Weight: 484.51
• MDL number: MFCD00050955
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329764798
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 96%
• 양식: solid
• 반응 적합성: core: ruthenium; reagent type: catalyst
• mp: 192-198 °C
• SMILES string: O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
• InChI: 1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
• InChI key: UMJDEUKQHKMAOI-UHFFFAOYSA-L

설명

일반 설명

Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl₂(dmso)₄] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.

애플리케이션

RuCl₂(dmso)₄ can be used as a catalyst for:

• The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
• The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable