39405

4-(Dimethylamino)pyridine

purum, ≥98.0% (NT)

• 동의어(들): N,N-Dimethylpyridin-4-amine, DMAP
• 실험식(Hill 표기법): C₇H₁₀N₂
• CAS Number: 1122-58-3
• Molecular Weight: 122.17
• Beilstein: 110354
• EC Number: 214-353-5
• MDL number: MFCD00006418
• UNSPSC 코드: 12352005
• PubChem Substance ID: 329755867
• NACRES: NA.22

속성

• grade: purum
• Quality Level: 200
• 분석: ≥98.0% (NT)
• 양식: crystals; pellets
• mp: 108-110 °C (lit.); 111-114 °C
• solubility: methanol: 0.1 g/mL, clear, colorless to almost colorless
• 작용기: amine
• SMILES string: CN(C)c1ccncc1
• InChI: 1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3
• InChI key: VHYFNPMBLIVWCW-UHFFFAOYSA-N

설명

일반 설명

4-(Dimethylamino)pyridine is generally employed as a catalyst in the acylation of amines, alcohols, enolates, and phenols. It can also be used in the esterification of carboxylic acids. It is known to exhibit good catalytic activity in non-polar solvents.

애플리케이션

4-(Dimethylamino)pyridine can be used:

• As a capping agent in the preparation of water-soluble gold nanoparticles.
• As an initiator in the polymerization of epoxy monomers.
• As an auxiliary reagent in the electroless preparation of gold nanotubes applicable in catalysis.
• As a catalyst in the preparation of γ- and δ-lactones via iodolactonization of γ,δ-unsaturated carboxylic acids.

A highly efficient catalyst for acylation reactions

기타 정보

Hypernucleophilic acylation catalyst. Review

안전성 정보

• 픽토그램: GHS06,GHS08,GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H331,H310,H315,H318,H370,H411
• 예방조치 성명서: P262 - P273 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1
• 표적 기관: Nervous system
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): 255.2 °F
• Flash Point (°C): 124 °C
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges