792527

Imidazole

anhydrous, free-flowing, Redi-Dri^™, ACS reagent, ≥99%

• 동의어(들): 1,3-Diaza-2,4-cyclopentadiene, Glyoxaline
• 실험식(Hill 표기법): C₃H₄N₂
• CAS Number: 288-32-4
• Molecular Weight: 68.08
• Beilstein: 103853
• EC Number: 206-019-2
• MDL number: MFCD00005183
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768341
• NACRES: NA.21

속성

• Grade: ACS reagent; anhydrous
• Quality Level: 200
• vapor pressure: <1 mmHg ( 20 °C)
• 제품 라인: Redi-Dri^™
• 분석: ≥99%
• 양식: solid
• 품질: free-flowing
• 불순물: ≤0.2% water
• 무기 잔류물: ≤0.1%
• pH: 9.5-11.0 (25 °C, 5% in H₂O)
• pKa(25 °C): 6.95
• bp: 256 °C (lit.)
• mp: 88-91 °C (lit.)
• 양이온 미량물: Fe: ≤0.001%
• SMILES string: c1c[nH]cn1
• InChI: 1S/C3H4N2/c1-2-5-3-4-1/h1-3H,(H,4,5)
• InChI key: RAXXELZNTBOGNW-UHFFFAOYSA-N

설명

애플리케이션

Excellent for buffers in the range of pH 6.2-7.8

Imidazole can be used as a proton transfer agent in the synthesis of porous organic polymers because of its amphiprotic nature and fast proton transfer behavior.
Imidazole can be used as a catalyst in the following      

• Silylation of alcohols, carboxylic acids, and amines in the presence of silyl chloride in DMF.      
• To prepare acid chlorides from the corresponding carboxylic acids and phosgene.      
• Imidazole-PPh₃/I₂ catalytic system used in the conversion of alcohols into iodides.      
• Imidazole-PPh₃/I₂ is used in the diol deoxygenation reaction.      

법적 정보

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

안전성 정보

• 픽토그램: GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H302,H314,H360D
• 예방조치 성명서: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1C
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 2
• Flash Point (°F): 293.0 °F - closed cup
• Flash Point (°C): 145 °C - closed cup