208221

Iodine monochloride

reagent grade, ≥95%

• 동의어(들): Chloroiodide
• Linear Formula: ICl
• CAS Number: 7790-99-0
• Molecular Weight: 162.36
• EC Number: 232-236-7
• MDL number: MFCD00011354
• UNSPSC 코드: 12352300
• PubChem Substance ID: 329752040
• NACRES: NA.21
• Grade: reagent grade

속성

• Grade: reagent grade
• Quality Level: 200
• 분석: ≥95%
• 양식: solid or liquid
• bp: 97.4 °C (lit.)
• density: 3.24 g/mL at 25 °C (lit.)
• 저장 온도: 2-8°C
• SMILES string: ClI
• InChI: 1S/ClI/c1-2
• InChI key: QZRGKCOWNLSUDK-UHFFFAOYSA-N

설명

일반 설명

Iodine monochloride is an interhalogen compound.[1] It forms various complexes with ethyl, isopropyl and t-butylbenzenes.[2] Electrically conducting solution of ICl is obtained on dissolution of ICl in polar solvents.[3] ICl is a green oxidizing agent and participates in the following transformations:[4]

• aldose hemiacetals to the corresponding aldose lactones
• diarylmethanols to the corresponding diarylmethanones
• arylalkylmethanols to the corresponding arylalkylmethanones
• dialkylmethanols to the corresponding dialkylmethanones

애플리케이션

Iodine monochloride (ICl) may be employed as a reagent in the following processes:

• Halogenation of methoxy and dimethoxybenzenes[3]
• Synthesis of flavones.[5]
• Preparation of 1-naphthaldehydes.[1]

It may be used as an iodinating agent in the conversion of alkylboranes to alkyl iodides.[6]

안전성 정보

• 픽토그램: GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H314,H335
• 예방조치 성명서: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable