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254363

Sigma-Aldrich

Methylmagnesium iodide solution

3.0 M in diethyl ether

Synonym(s):

Iodomethylmagnesium, Methylmagnesium iodine

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20 MG
₩504,658

About This Item

Linear Formula:
CH3MgI
CAS Number:
917-64-6
Molecular Weight:
166.24
Beilstein:
1209226
MDL number:
MFCD00001026
UNSPSC Code:
12352103
PubChem Substance ID:
24855379
NACRES:
NA.22

₩504,658

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Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

3.0 M in diethyl ether

density

1.261 g/mL at 25 °C

SMILES string

C[Mg]I

InChI

1S/CH3.HI.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AUPXBVDHVRZMIB-UHFFFAOYSA-M

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Show Differences

1 of 4

This Item
189898293091224391
Methylmagnesium iodide solution 3.0 M in diethyl ether

254363

Methylmagnesium iodide solution

Methylmagnesium bromide solution 3.0 M in diethyl ether

189898

Methylmagnesium bromide solution

Methyl-d3-magnesium iodide solution 1.0 M in diethyl ether, 99 atom % D

293091

Methyl-d3-magnesium iodide solution

Propylmagnesium chloride solution 2.0 M in diethyl ether

224391

Propylmagnesium chloride solution

concentration

3.0 M in diethyl ether

concentration

3.0 M in diethyl ether

concentration

1.0 M in diethyl ether

concentration

2.0 M in diethyl ether

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

density

1.261 g/mL at 25 °C

density

1.035 g/mL at 25 °C

density

0.871 g/mL at 25 °C

density

0.827 g/mL at 25 °C

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

-

reaction suitability

reaction type: Grignard Reaction

Application

Methylmagnesium iodide solution can be used:
  • To prepare cis-1,2-dialkylcyclopropanols by treating with titanium(IV) alkoxide and carboxylic esters.[1]
  • In stereospecific Ni catalyzed Kumada cross-coupling reactions of benzylic ethers.[2]
  • To prepare 2,4-disubstituted selenochromenes by reacting with 1-benzoselenopyrylium salts.[3]
  • In one of the key synthetic steps for the preparation of 7β-methyl-substituted 5-androstene derivatives from 3β-acetoxyandrost-5-en-17-one stereoselectively.[4]

Signal Word

Danger

Hazard Statements

H224,H260,H314,H336

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    Certificates of Analysis (COA)

    Lot/Batch Number
    SHBK9708
    SHBH8848
    SHBG5857V
    12896BPV
    12896BP

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