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298433

Sigma-Aldrich

Dichloroborane methyl sulfide complex

in excess methyl sulfide

Synonym(s):

Boron dichloride methyl sulfide complex, Dichloro(dimethyl sulfide)(hydro)boron, Dichloro(dimethyl sulfide)borane, Dichloroborane dimethyl sulfide

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About This Item

Linear Formula:
(CH3)2S·BHCl2
CAS Number:
Molecular Weight:
144.86
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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Quality Level

reaction suitability

reagent type: reductant

density

1.255 g/mL at 25 °C (lit.)

functional group

thioether

SMILES string

C[S+](C)[BH-](Cl)Cl

InChI

1S/C2H7BCl2S/c1-6(2)3(4)5/h3H,1-2H3

InChI key

UMDZKXAEAKAIPA-UHFFFAOYSA-N

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This Item
W342203W376604W314820
organoleptic

fatty; green; melon; floral

organoleptic

butter; spicy

organoleptic

cucumber; fresh; green; melon; citrus; vegetable

organoleptic

green; tropical; waxy; fruity; pear; pear; sweet

grade

FG, Kosher

grade

FG, Halal, Kosher

grade

FG, Halal, Kosher

grade

FG, Halal, Kosher

biological source

synthetic

biological source

synthetic

biological source

synthetic

biological source

synthetic

food allergen

no known allergens

food allergen

no known allergens

food allergen

no known allergens

food allergen

no known allergens

documentation

see Safety & Documentation for available documents

documentation

see Safety & Documentation for available documents

documentation

see Safety & Documentation for available documents

documentation

see Safety & Documentation for available documents

assay

≥89%

assay

≥95%

assay

≥95%

assay

≥95%

Application

Reactant for:
  • Hydroboration reactions
  • Pyrolysis reactions
  • Addition reactions
  • Preparation of unsymmetrical borafluorenes
  • Cyclization reactions
  • Dismutation followed by haloboration of azadiboriridine to give boron-nitrogen clusters
  • Markovnikov hydroboration

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

75.2 °F - closed cup

Flash Point(C)

24 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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