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766135

Sigma-Aldrich

3-Butenylzinc bromide solution

0.6 M in THF

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About This Item

Empirical Formula (Hill Notation):
C4H7BrZn
CAS Number:
Molecular Weight:
200.39
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
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form

solution

Quality Level

reaction suitability

core: zinc
reagent type: catalyst
reaction type: Negishi Coupling

concentration

0.6 M in THF

impurities

<5% free chloride

functional group

allyl

storage temp.

2-8°C

SMILES string

Br[Zn]CCC=C

InChI

1S/C4H7.BrH.Zn/c1-3-4-2;;/h3H,1-2,4H2;1H;/q;;+1/p-1

InChI key

BBPYRBGCVVBQPH-UHFFFAOYSA-M

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This Item
766127499552720755
reaction suitability

core: zinc, reagent type: catalyst
reaction type: Negishi Coupling

reaction suitability

core: zinc, reagent type: catalyst
reaction type: Negishi Coupling, reagent type: derivatization reagent
reaction type: Negishi Coupling

reaction suitability

core: zinc, reagent type: catalyst

reaction suitability

core: zinc, reagent type: catalyst

form

solution

form

liquid

form

-

form

solid

functional group

allyl

functional group

fluoro

functional group

-

functional group

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

concentration

0.6 M in THF

concentration

0.6 M in THF

concentration

5 g/dL Zn+2 in THF

concentration

-

Application

Nucleophlic reagent applicable for substitution and addition reactions. Also could be used in cross coupling reactions (Negishi couplings).

technical-documents

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-5.8 °F

Flash Point(C)

-21 °C


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