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About This Item

Empirical Formula (Hill Notation):
C39H46N3O3PPdS
CAS Number:
Molecular Weight:
774.26
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
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Quality Level

Assay

≥95%

form

powder

feature

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

SMILES string

[Pd+2]c4c(cccc4)c5c(cccc5)[N-H].P(C(C)(C)C)(c2c(cccc2)c3c(cccc3N(C)C)N(C)C)c1ccccc1.[S](=O)(=O)([O-])C

InChI

1S/C26H33N2P.C12H9N.CH4O3S.Pd/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h8-19H,1-7H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-1;;+2/p-1

InChI key

IYOQFXCZIJAOED-UHFFFAOYSA-M

Application

As the Pd G3 complex, this ligand from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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