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747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Synonym(s):

[Ir{dF(CF3)ppy}2(dtbpy)]PF6, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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200 MG
₩225,229

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200 MG
₩225,229

About This Item

Empirical Formula (Hill Notation):
C42H34F16IrN4P
CAS Number:
Molecular Weight:
1121.91
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22

₩225,229


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form

solid

Quality Level

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

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1 of 4

This Item
Y0001954Y00019501535766
manufacturer/tradename

EDQM

manufacturer/tradename

EDQM

manufacturer/tradename

EDQM

manufacturer/tradename

USP

grade

pharmaceutical primary standard

grade

pharmaceutical primary standard

grade

pharmaceutical primary standard

grade

pharmaceutical primary standard

application(s)

pharmaceutical

application(s)

-

application(s)

pharmaceutical

application(s)

pharmaceutical (small molecule)

format

neat

format

neat

format

neat

format

neat

API family

phosphatidylethanolamine

API family

phosphatidylethanolamine

API family

phosphatidylcholine

API family

phosphatidylethanolamine

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

Application

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.[1][2][3][4][5]It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.[3]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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