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About This Item
Empirical Formula (Hill Notation):
C12H17NO5Si
CAS Number:
Molecular Weight:
283.35
Beilstein/REAXYS Number:
4320585
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.22
Product Name
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate, ≥97.0%
Quality Level
assay
≥97.0%
form
crystals
mp
35-40 °C
application(s)
peptide synthesis
functional group
carbonate
nitro
storage temp.
2-8°C
SMILES string
C[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
InChI
1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI key
ZAQWGGKIMQIVGM-UHFFFAOYSA-N
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Application
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:
- A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
- A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.
Other Notes
Reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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