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697230

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Name: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Brand: ALDRICH

동의어(들):

Pd(dppf)Cl₂

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모든 사진(3)

About This Item

Linear Formula:

(C₁₇H₁₄P)₂Fe · PdCl₂

CAS Number:

72287-26-4

Molecular Weight:

731.70

EC Number:

460-040-3

MDL number:

MFCD00015757

UNSPSC 코드:

12161600

PubChem Substance ID:

329761901

NACRES:

NA.22

추천 제품

Slide 1 of 10

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Sigma-Aldrich

379670

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

Sigma-Aldrich

701602

[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

Sigma-Aldrich

208671

Bis(triphenylphosphine)palladium(II) dichloride

Sigma-Aldrich

216666

Tetrakis(triphenylphosphine)palladium(0)

Sigma-Aldrich

412740

Bis(triphenylphosphine)palladium(II) dichloride

Sigma-Aldrich

473294

Bis(pinacolato)diboron

Sigma-Aldrich

205869

Palladium(II) acetate

Sigma-Aldrich

328774

Tris(dibenzylideneacetone)dipalladium(0)

Sigma-Aldrich

741248

Bis(triphenylphosphine)palladium(II) dichloride

Sigma-Aldrich

676578

Bis(tri-tert-butylphosphine)palladium(0)

양식

powder

Quality Level

200

반응 적합성

core: palladium
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

mp

266-283 °C (lit.)

SMILES string

[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

JCWIWBWXCVGEAN-UHFFFAOYSA-L

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애플리케이션

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl₂ may be used as an effective palladium catalyst in the following reactions:

Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [¹¹C]methyl iodide to form functionalized [¹¹C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

For small scale and high throughput uses, product is also available as ChemBeads (919780)