모든 사진(2)

주요 문서

모든 문서 보기

747130

Josiphos SL-J009-1 Pd G3

Name: Josiphos SL-J009-1 Pd G3
Brand: ALDRICH

동의어(들):

Josiphos SL-J009-1-G3-palladacycle, {(R)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine}[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

로그인조직 및 계약 가격 보기

모든 사진(2)

About This Item

실험식(Hill 표기법):

C₄₅H₆₅FeNO₃P₂PdS

CAS Number:

1702311-34-9

Molecular Weight:

924.28

MDL number:

MFCD27978424

UNSPSC 코드:

12161600

PubChem Substance ID:

329765813

NACRES:

NA.22

추천 제품

Slide 1 of 10

1 of 10

Sigma-Aldrich

88717

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

Sigma-Aldrich

88733

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

Sigma-Aldrich

761435

cataCXium^® A Pd G3

Sigma-Aldrich

792357

MorDalphos Pd G3

Sigma-Aldrich

804975

DTBPF-Pd-G3

Sigma-Aldrich

751618

MorDalphos

Sigma-Aldrich

701602

[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

Sigma-Aldrich

773905

RockPhos Pd G3

Sigma-Aldrich

697230

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Sigma-Aldrich

763381

XPhos Pd G3

양식

solid

Quality Level

100

특징

generation 3

반응 적합성

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

180-186 °C

작용기

phosphine

SMILES string

NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe]

InChI

1S/C27H47P2.C12H10N.C5H5.CH4O3S.Fe.Pd/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-2-4-5-3-1;1-5(2,3)4;;/h14,19-23H,8-13,15-18H2,1-7H3;1-6,8-9H,13H2;1-5H;1H3,(H,2,3,4);;/q;;;;;+1/p-1/t21-;;;;;/m1...../s1

InChI key

GJFJVCUFUWXFEB-RPDSBUJNSA-M

일반 설명

Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

애플리케이션

Total Syntheses of N-Paspaline and N-Emindole PB: Discusses the use of various catalysts including RuPhos and Josiphos ligands for synthesizing complex molecular structures (Radical-Polar Crossover Cyclizations, 2020).

Unprotected Indazoles Are Resilient to Ring-Opening Isomerization: A Case Study on Catalytic C-S Couplings in the Presence of Strong Base: Utilizes Josiphos SL-J009-1 Pd-G3 for catalytic C-S coupling reactions under strong base conditions (The Journal of Organic Chemistry, 2017).

Synthesis and characterization of an isopropylBippyPhos precatalyst: Compares various phosphine ligands including XPhos and Josiphos for catalytic activity in organic syntheses (Tetrahedron, 2022).

Novel quorum sensing inhibitors targeting PqsR: Mentions the experimental use of Josiphos ligands in the synthesis of potential pharmaceutical compounds (2020, University of Saarland).