157457

3,5-Di-tert-butyl-o-benzoquinone

98%

• Synonym(s): 3,5-Bis(1,1-dimethylethyl)-3,5-cyclohexadiene-1,2-dione, 3,5-Di-t-butyl-o-quinone, 3,5-Di-tert-butyl-1,2-benzoquinone, 3,5-Di-tert-butyl-o-quinone, 3,5-Di-tert-butylcyclohexa-3,5-diene-1,2-dione, 3,5-Di-tert-butylquinone, 3,5-Ditert-butylcyclohexa-3,5-diene-1,2-dione, 4,6-Di-tert-butyl-1,2-benzoquinone, 4,6-Di-tert-butyl-o-benzoquinone
• Linear Formula: [(CH₃)₃C]₂C₆H₂(=O)₂
• CAS Number: 3383-21-9
• Molecular Weight: 220.31
• Beilstein: 2047944
• EC Number: 222-189-0
• MDL number: MFCD00001647
• UNSPSC Code: 12352100
• PubChem Substance ID: 24849680
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• form: solid
• mp: 112-114 °C (lit.)
• SMILES string: CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C
• InChI: 1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3
• InChI key: NOUZOVBGCDDMSX-UHFFFAOYSA-N
• Gene Information: human ... ACHE(43), BCHE(590), CES1(1066)

Description

General description

Reactions of the phosphinidene-bridged complexes [Fe₂(η⁵-C₅H₅)₂(μ-PR)(μ-CO)(CO)₂] (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.

Application

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves