159069

4-Chloroanisole

99%

• Linear Formula: ClC₆H₄OCH₃
• CAS Number: 623-12-1
• Molecular Weight: 142.58
• Beilstein: 1858901
• EC Number: 210-772-2
• MDL number: MFCD00000616
• UNSPSC Code: 12352100
• PubChem Substance ID: 24849788
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 99%
• form: liquid
• refractive index: n20/D 1.535 (lit.)
• bp: 198-202 °C (lit.)
• mp: −18 °C (lit.)
• density: 1.164 g/mL at 25 °C (lit.)
• functional group: chloro
• SMILES string: COc1ccc(Cl)cc1
• InChI: 1S/C7H7ClO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
• InChI key: YRGAYAGBVIXNAQ-UHFFFAOYSA-N

Description

General description

4-Chloroanisole is an electron-rich chloroarene. It undergoes Ullmann-type homocoupling catalyzed by in situ generated Pd colloids. Reaction of 4-chloroanisole with Cu(II)-smectite in n-hexane, carbon tetrachloride or dichloromethane has been studied. The nucleophilic photosubstitution reactions, photocyanation and photohydrolysis of 4-chloroanisole has been studied by time resolved spectroscopy.

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 165.2 °F - closed cup
• Flash Point(C): 74 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves