419613

2-Methyl-1-propenylmagnesium bromide solution

0.5 M in THF

• Synonym(s): (2-Methylpropenyl)magnesium bromide, 2,2-Dimethylvinylmagnesium bromide, Isobutenylmagnesium bromide
• Linear Formula: (CH₃)₂C=CHMgBr
• CAS Number: 38614-36-7
• Molecular Weight: 159.31
• MDL number: MFCD00209600
• UNSPSC Code: 12352103
• PubChem Substance ID: 24866265
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in THF
• density: 0.952 g/mL at 25 °C
• SMILES string: C\C(C)=C\[Mg]Br
• InChI: 1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
• InChI key: BKVIQODYSREJQH-UHFFFAOYSA-M

Description

General description

2-Methyl-1-propenylmagnesiumbromide is a heterocyclic organic compound. It is used as a Grignard reagent in chemical synthesis.

Application

Used in a study of a palladium-catalyzed coupling with aryl tosylates.

Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H261,H302,H314,H335,H351
• Precautionary Statements: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point(F): 5.0 °F - closed cup
• Flash Point(C): -15 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves