510017

(Oxydi-2,1-phenylene)bis(diphenylphosphine)

98%

• Synonym(s): Bis[(2-diphenylphosphino)phenyl] ether, DPEPhos
• Linear Formula: O[C₆H₄P(C₆H₅)₂]₂
• CAS Number: 166330-10-5
• Molecular Weight: 538.55
• MDL number: MFCD00233863
• UNSPSC Code: 12352112
• PubChem Substance ID: 24873467
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• reaction suitability: reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: Heck Reaction; reagent type: ligand; reaction type: Hydroaminations; reagent type: ligand; reaction type: Negishi Coupling; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 184-187 °C (lit.)
• functional group: phosphine
• greener alternative category: , Aligned
• SMILES string: O(c1ccccc1P(c2ccccc2)c3ccccc3)c4ccccc4P(c5ccccc5)c6ccccc6
• InChI: 1S/C36H28OP2/c1-5-17-29(18-6-1)38(30-19-7-2-8-20-30)35-27-15-13-25-33(35)37-34-26-14-16-28-36(34)39(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
• InChI key: RYXZOQOZERSHHQ-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves