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901409

Sigma-Aldrich

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

Synonym(s):

Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C42H40F10IrN4P
CAS Number:
1335047-34-1
Molecular Weight:
1013.97
MDL number:
MFCD31619196
UNSPSC Code:
12161600
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

450 nm

InChI key

XAJPUJWOMJJPNU-UHFFFAOYSA-N

Related Categories

Application

[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides

Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands

Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ5323
MKCK6936

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