121967

Aminoacetaldehyde dimethyl acetal

99%

• Synonyme(s) : 2,2-Dimethoxyethylamine
• Formule linéaire : NH₂CH₂CH(OCH₃)₂
• CAS Number: 22483-09-6
• Poids moléculaire : 105.14
• Beilstein: 741868
• Numéro CE : 245-026-5
• Numéro MDL: MFCD00008135
• Code UNSPSC : 12352100
• ID de substance PubChem : 24847473
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 200
• Essai: 99%
• Indice de réfraction: n20/D 1.417 (lit.)
• pb: 135-139 °C/95 mmHg (lit.)
• Densité: 0.965 g/mL at 25 °C (lit.)
• Groupe fonctionnel: acetal; amine; ether
• Chaîne SMILES: COC(CN)OC
• InChI: 1S/C4H11NO2/c1-6-4(3-5)7-2/h4H,3,5H2,1-2H3
• Clé InChI: QKWWDTYDYOFRJL-UHFFFAOYSA-N

Description

Description générale

Aminoacetaldehyde dimethyl acetal reacts with sulfone, followed by hydrolysis and reductive amination by adding desired piperazine derivative to yield piperazine derivatives of 2-furanyl[1,2,4]triazolo[1,5-a][1,3,5]triazine.

Aminoacetaldehyde dimethyl acetal is used as a building block for the synthesis of various acylated and sufonylated oxyenamides.

Application

Aminoacetaldehyde dimethyl acetal was used in a study to develop a fluorescent substrate for aldehyde dehydrogenase. It was used in preparation of chitosan-dendrimer hybrids having various functional groups such as carboxyl, ester and poly(ethylene glycol). It was used in an efficient 3-step synthesis of a bicyclic proline analog from L-ascorbic acid and in 3-component reaction catalyzed by MgClO₄ leading to α-aminophosphonates.

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H226,H314
• Conseils de prudence: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Flam. Liq. 3 - Skin Corr. 1B
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 111.2 °F - closed cup
• Point d'éclair (°C): 44 °C - closed cup
• Équipement de protection individuelle: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter