122440

Thianthrene

97%

• Synonyme(s) : Dibenzodithiodioxane
• Formule empirique (notation de Hill) : C₁₂H₈S₂
• CAS Number: 92-85-3
• Poids moléculaire : 216.32
• Beilstein: 83046
• Numéro CE : 202-197-0
• Numéro MDL: MFCD00005065
• Code UNSPSC : 12352100
• ID de substance PubChem : 24847488
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Essai: 97%
• Forme: solid
• pb: 364-366 °C (lit.)
• Pf: 151-155 °C (lit.)
• Solubilité: DMF: soluble; H₂O: insoluble
• Chaîne SMILES: S1c2ccccc2Sc3ccccc13
• InChI: 1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H
• Clé InChI: GVIJJXMXTUZIOD-UHFFFAOYSA-N

Description

Description générale

Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.

Application

Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)