14353

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

≥95.0%

• Synonyme(s) : 5-Norbornene-2,3-dicarboxylic anhydride
• Formule empirique (notation de Hill) : C₉H₈O₃
• CAS Number: 826-62-0
• Poids moléculaire : 164.16
• Beilstein: 150228
• Numéro CE : 212-557-9
• Numéro MDL: MFCD00151106
• Code UNSPSC : 12352100
• ID de substance PubChem : 57647148
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Essai: ≥95.0%
• Solubilité: diethyl ether: 0.1 g/10 mL, clear, colorless
• Chaîne SMILES: O=C1OC(=O)[C@H]2[C@@H]3C[C@@H](C=C3)[C@@H]12
• InChI: 1S/C9H8O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h1-2,4-7H,3H2/t4-,5+,6-,7+
• Clé InChI: KNDQHSIWLOJIGP-UMRXKNAASA-N

Description

Description générale

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride reacts with methyl aminomethyllambertianate to give amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent.

Application

• Sustainable chemical processes with Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride: Research by Kharitonov et al. (2012) explores synthetic transformations of higher terpenoids, employing Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Their work focuses on creating new cytotoxic agents, contributing to sustainable methodologies in organic synthesis (Kharitonov et al., 2012).
• Organic synthesis intermediate: Birchall et al. (2021) present a study on Himic Anhydride, utilizing a retro Diels-Alder reaction to demonstrate the application of Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride in teaching advanced organic laboratory techniques. This work includes an accompanying NMR study to further support the educational aspect of organic synthesis (Birchall et al., 2021).

Informations sur la sécurité

• Pictogrammes: GHS08,GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H317,H318,H334
• Conseils de prudence: P261 - P272 - P280 - P284 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable