167169

3-Bromo-1-propanol

97%

• Synonyme(s) : Trimethylene bromohydrin
• Formule linéaire : Br(CH₂)₃OH
• CAS Number: 627-18-9
• Poids moléculaire : 138.99
• Beilstein: 969160
• Numéro CE : 210-986-6
• Numéro MDL: MFCD00002942
• Code UNSPSC : 12352100
• ID de substance PubChem : 24850196
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Essai: 97%
• Forme: liquid
• Indice de réfraction: n20/D 1.488 (lit.)
• pb: 62 °C/5 mmHg (lit.)
• Densité: 1.537 g/mL at 25 °C (lit.)
• Groupe fonctionnel: bromo; hydroxyl
• Température de stockage: 2-8°C
• Chaîne SMILES: OCCCBr
• InChI: 1S/C3H7BrO/c4-2-1-3-5/h5H,1-3H2
• Clé InChI: RQFUZUMFPRMVDX-UHFFFAOYSA-N

Description

Description générale

Reaction between 3-bromo-1-propanol, phenol and a series of phenols having substituents in 4-position has been studied in micellar media and in microemulsions based on cationic or a nonionic surfactant.

3-Bromo-1-propanol is an electrophile used as a substrate in nucleophilic substitution reactions and in the redox polymerization.

Application

3-Bromo-1-propanol was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. It was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.

Recently used as a grafting agent in the synthesis of recyclable reagents for Swern oxidation

Informations sur la sécurité

• Pictogrammes: GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H302,H318
• Conseils de prudence: P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1
• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 149.0 °F - closed cup
• Point d'éclair (°C): 65 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter