230200

Lithium borohydride solution

2.0 M in THF

• Synonyme(s) : Lithium boron hydride, Lithium hydroborate
• Formule linéaire : LiBH₄
• CAS Number: 16949-15-8
• Poids moléculaire : 21.78
• Numéro MDL: MFCD00011088
• Code UNSPSC : 12352302
• ID de substance PubChem : 24853783
• Nomenclature NACRES : NA.22

Propriétés

• Forme: liquid
• Niveau de qualité: 200
• Pertinence de la réaction: reagent type: reductant
• Concentration: 2.0 M in THF
• Densité: 0.896 g/mL at 25 °C
• Chaîne SMILES: [Li+].[H][B-]([H])([H])[H]
• InChI: 1S/BH4.Li/h1H4;/q-1;+1
• Clé InChI: UUKMSDRCXNLYOO-UHFFFAOYSA-N

Description

Application

Lithium borohydride solution (2M in THF) has been used for the reduction of 5-benzylidene-2,4-thiazolidinediones and 5-benzylidene-4-oxo-2-thiazolidinethiones to form 5-benzyl-2,4-thiazolidinediones and 5-benzyl-4-oxo-2-thiazolidinethiones, respectively.

Reactant for:

• Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes
• Mechano-chemical metathesis reactions
• Noncatalytic hydrolysis for hydrogen generation
• Growth of large gold monolayer protected-clusters
• Anion substitution reactions
• Dehydrogenation reactions

Conditionnement

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Informations légales

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Informations sur la sécurité

• Pictogrammes: GHS02,GHS08,GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H260,H302,H314,H335,H336,H351
• Conseils de prudence: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Organes cibles: Central nervous system, Respiratory system
• Risques supp: EUH019
• Code de la classe de stockage: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): -0.4 °F - closed cup
• Point d'éclair (°C): -18 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter