302937

Perfluoro(methylcyclohexane)

technical grade, 90%

• Synonyme(s) : (Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane
• Formule linéaire : C₆F₁₁CF₃
• CAS Number: 355-02-2
• Poids moléculaire : 350.05
• Beilstein: 1915981
• Numéro CE : 206-573-5
• Numéro MDL: MFCD00001468
• Code UNSPSC : 12352100
• ID de substance PubChem : 24858283
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: technical grade
• Niveau de qualité: 100
• Essai: 90%
• Forme: liquid
• Indice de réfraction: n17/D 1.285 (lit.)
• pb: 76 °C (lit.)
• Densité: 1.787 g/mL at 25 °C (lit.)
• Groupe fonctionnel: fluoro
• Chaîne SMILES: FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
• InChI: 1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
• Clé InChI: QIROQPWSJUXOJC-UHFFFAOYSA-N

Description

Description générale

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Application

Perfluoro(methylcyclohexane) can be used as:

• A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
• A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Informations sur la sécurité

• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves