418293

Sodium thiophenolate

technical grade, 90%

• Synonyme(s) : Benzenethiol sodium salt, Sodium thiophenoxide, Thiophenol sodium salt
• Formule linéaire : C₆H₅SNa
• CAS Number: 930-69-8
• Poids moléculaire : 132.16
• Beilstein: 3597302
• Numéro CE : 213-224-0
• Numéro MDL: MFCD00066460
• Code UNSPSC : 12352100
• ID de substance PubChem : 24866217
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: technical grade
• Niveau de qualité: 200
• Essai: 90%
• Forme: powder
• Pf: >300 °C (lit.)
• Chaîne SMILES: [Na]Sc1ccccc1
• InChI: 1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
• Clé InChI: RZWQDAUIUBVCDD-UHFFFAOYSA-M

Description

Description générale

Sodium thiophenolate can be prepared from the reaction of sodium and thiophenol in diethyl ether.

Application

Sodium thiophenolate has been used for the synthesis of MCoTI-I and MCoTI-II cyclotides, which are naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors. It may be employed in the following studies:

• As probe for the immunoassay and for the detection of label-free protein by surface-enhanced Raman scattering (SERS).
• Preparation of new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (C--N--N)Pt(II) thiophenolate complexes.
• Synthesis of 1,3,5,7,9-pentakis(4-methoxyphenylthio)corannulene, 1,3,5,7,9-pentakis(2-naphthylthio)corannulene and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene.
• Synthesis of Et₄N⁺ salts of homoleptic arylthiolate Ti(IV) complex, [Ti(SPh)₆]^2-.

Informations sur la sécurité

• Pictogrammes: GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H314
• Conseils de prudence: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Classification des risques: Skin Corr. 1B
• Code de la classe de stockage: 8A - Combustible corrosive hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges