680850

Di-(4-chlorobenzyl)azodicarboxylate

97%

• Synonyme(s) : Bis-(4-chlorobenzyl)azodicarboxylate, DCAD
• Formule empirique (notation de Hill) : C₁₆H₁₂Cl₂N₂O₄
• CAS Number: 916320-82-6
• Poids moléculaire : 367.18
• Numéro MDL: MFCD27995640
• Code UNSPSC : 12352101
• ID de substance PubChem : 24885598
• Nomenclature NACRES : NA.22

Propriétés

• Essai: 97%
• Forme: solid
• Pf: 108-112 °C
• Groupe fonctionnel: azo; chloro
• Chaîne SMILES: O=C(/N=N\C(OCC1=CC=C(Cl)C=C1)=O)OCC2=CC=C(Cl)C=C2
• InChI: 1S/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2/b20-19-
• Clé InChI: UIFGGABIJBWRMG-VXPUYCOJSA-N

Description

Description générale

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Application

Di-(4-chlorobenzyl)azodicarboxylate (DCAD) is a novel, stable, solid alternative to DEAD and DIAD for a variety of Mitsunobu couplings giving a readily separable hydrazine byproduct that can be recycled.

Reactant for preparation of:

• Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters
• Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium
• DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H317
• Conseils de prudence: P280
• Classification des risques: Skin Sens. 1
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable