710857

Iron(III) chloride solution

0.2 M in 2-methyltetrahydrofuran

• Synonyme(s) : Ferric chloride solution
• Formule linéaire : FeCl₃
• CAS Number: 7705-08-0
• Poids moléculaire : 162.20
• Numéro MDL: MFCD00011005
• Code UNSPSC : 12161600
• ID de substance PubChem : 329763016
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solution
• Niveau de qualité: 100
• Pertinence de la réaction: core: iron; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Concentration: 0.2 M in 2-methyltetrahydrofuran
• Indice de réfraction: n20/D 1.414
• Densité: 0.868 g/mL at 25 °C
• Autre catégorie plus écologique: , Aligned
• Chaîne SMILES: Cl[Fe](Cl)Cl
• InChI: 1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
• Clé InChI: RBTARNINKXHZNM-UHFFFAOYSA-K

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl₃ is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:

• As a mild oxidant for phenolic coupling reaction.
• In dimerizing aryllithiumsand ketone enolates.
• As a mild Lewis acid catalyst to catalyzes ene reactions.
• In Nazarov cyclizations, Michael additions, and acetonation reactions.

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H290,H302,H315,H318
• Conseils de prudence: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
• Risques supp: EUH019
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 14.0 °F - closed cup
• Point d'éclair (°C): -10.0 °C - closed cup