900402

SLAP HydroQuinoxaline

95%

• Synonyme(s) : trans-N¹-Benzyl-N¹-((trimethylsilyl)methyl)cyclohexane-1,2-diamine
• Formule empirique (notation de Hill) : C₁₇H₃₀N₂Si
• Poids moléculaire : 290.52
• Code UNSPSC : 12352103
• Nomenclature NACRES : NA.22

Propriétés

• Essai: 95%
• Forme: liquid
• Indice de réfraction: n/D 1.5222
• Densité: 0.961 g/mL
• Groupe fonctionnel: amine; phenyl
• Température de stockage: −20°C

Description

Application

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

Autres remarques

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

Informations sur la sécurité

• Code de la classe de stockage: 10 - Combustible liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): >230.0 °F
• Point d'éclair (°C): > 110 °C