911208

1-Hydrosilatrane

≥95%

• Synonyme(s) : Hydrosilatrane, Silatrane
• Formule empirique (notation de Hill) : C₆H₁₃NO₃Si
• CAS Number: 283-60-3
• Poids moléculaire : 175.26
• Numéro MDL: MFCD22056310
• Code UNSPSC : 41116107
• Nomenclature NACRES : NA.22

Propriétés

• Essai: ≥95%
• Forme: powder or crystals
• Pertinence de la réaction: reagent type: reductant
• Pf: 249-256 °C
• Température de stockage: −20°C
• InChI: 1S/C6H12NO3Si/c1-4-8-11-9-5-2-7(1)3-6-10-11/h1-6H2
• Clé InChI: XBRVPWBNRAPVCC-UHFFFAOYSA-N

Description

Application

1-Hydrosilatrane is an air- and moisture-stable hydride reducing reagent that exhibits high functional group compatibility. The Adler group has used 1-hydrosilatrane for the reduction of ketones and aldehydes as well as the direct reductive amination of ketones under mild conditions.

Autres remarques

Chiral Bronsted Acid-Catalyzed Metal-Free Asymmetric Direct Reductive Amination Using 1-Hydrosilatrane

Silatrane as a Practical and Selective Reagent for the Reduction of Aryl Aldehydes to Benzylic Alcohols

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable