A88255

p-Anisidine

99%

• Synonyme(s) : 4-Aminoanisole, 4-Methoxyaniline
• Formule linéaire : CH₃OC₆H₄NH₂
• CAS Number: 104-94-9
• Poids moléculaire : 123.15
• Beilstein: 471556
• Numéro MDL: MFCD00007864
• Code UNSPSC : 12352100
• ID de substance PubChem : 24891372
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 200
• Essai: 99%
• Forme: solid
• Température d'inflammation spontanée: 959 °F
• pb: 240-243 °C (lit.)
• Pf: 56-59 °C (lit.)
• Chaîne SMILES: COc1ccc(N)cc1
• InChI: 1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
• Clé InChI: BHAAPTBBJKJZER-UHFFFAOYSA-N

Description

Application

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:

• In the diastereoselective and enantioselective synthesis of CF₃-substituted azoridines catalyzed by a chiral Bronsted acid.
• To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)₃.
• As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
• To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.

Informations sur la sécurité

• Pictogrammes: GHS06,GHS08,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H300 + H310 + H330,H350,H373,H400
• Conseils de prudence: P202 - P260 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Classification des risques: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Carc. 1B - STOT RE 2
• Code de la classe de stockage: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 251.6 °F - closed cup
• Point d'éclair (°C): 122 °C - closed cup