243434

Tin

granular, 0.425-2.0 mm particle size, ≥99.5%, ACS reagent

• Synonyme(s) : Sn
• Formule empirique (notation de Hill) : Sn
• CAS Number: 7440-31-5
• Poids moléculaire : 118.71
• Numéro CE : 231-141-8
• Numéro MDL: MFCD00133862
• Code UNSPSC : 11101716
• ID de substance PubChem : 24854615
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: ACS reagent
• Niveau de qualité: 200
• Essai: ≥99.5%
• Forme: granular
• Pertinence de la réaction: core: tin; reagent type: catalyst
• Résistivité: 11 μΩ-cm, 20°C
• Taille des particules: 0.425-2.0 mm
• pb: 2270 °C (lit.)
• Pf: 231.9 °C (lit.)
• Densité: 7.310 g/mL at 25 °C (lit.)
• Traces de cations: As: ≤1 ppm; Cu: ≤0.005%; Fe: ≤0.01%; Pb: ≤0.005%; Sb: ≤0.02%
• Chaîne SMILES: [Sn]
• InChI: 1S/Sn
• Clé InChI: ATJFFYVFTNAWJD-UHFFFAOYSA-N

Description

Description générale

Tin (Sn) is a silvery-white metal that is malleable and ductile at ordinary temperatures. It is used as a catalyst in organic synthesis. It is also used in various sectors, such as nuclear energy, plastics, polymers, agriculture, biochemistry, and in glassmaking.

Application

Applied in the solid state synthesis of a Zintl phase, SrSn₃Sb₄, with an anionic channel framework of 30-membered rings.

Tin can be used in the following:      

• With HCl, it reduces a variety of functional groups.
• Stereoselective allylation of carbonyl compounds.     
• In situ generations of tin enolates for directed aldol reactions.
• Preparation of organotin reagents.

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)