115460

Fluoroacetone

98%

• Synonym(s): α-Fluoroacetone, 1-Fluoro-2-propanone, Fluoromethyl methyl ketone, Monofluoroacetone
• Linear Formula: CH₃COCH₂F
• CAS Number: 430-51-3
• Molecular Weight: 76.07
• EC Number: 207-064-0
• MDL number: MFCD00000451
• UNSPSC Code: 12352100
• PubChem Substance ID: 24847218
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• refractive index: n20/D 1.37 (lit.)
• bp: 75 °C (lit.)
• density: 1.054 g/mL at 25 °C (lit.)
• functional group: fluoro; ketone
• storage temp.: 2-8°C
• SMILES string: CC(=O)CF
• InChI: 1S/C3H5FO/c1-3(5)2-4/h2H2,1H3
• InChI key: MSWVMWGCNZQPIA-UHFFFAOYSA-N

Description

General description

Aldolizations of fluoroacetone with aldehydes mediated by organocatalyst yield products with high enantioselectivities.

Application

Fluoroacetone has been used as a catalyst to study the kinetics of the ketone-catalysed decomposition of peroxymonosulfuric acid (Caro′s acid).

Safety Information

• Pictograms: GHS02,GHS06
• Signal Word: Danger
• Hazard Statements: H225,H300 + H310 + H330
• Precautionary Statements: P210 - P262 - P280 - P301 + P310 + P330 - P302 + P352 + P310 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 44.6 °F - closed cup
• Flash Point(C): 7 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves