124133

3-Bromoquinoline

98%

• Empirical Formula (Hill Notation): C₉H₆BrN
• CAS Number: 5332-24-1
• Molecular Weight: 208.05
• Beilstein: 112939
• EC Number: 226-237-1
• MDL number: MFCD00006767
• UNSPSC Code: 12352100
• PubChem Substance ID: 24847599
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 98%
• form: liquid
• refractive index: n20/D 1.664 (lit.)
• bp: 274-276 °C (lit.)
• mp: 13-15 °C (lit.)
• density: 1.533 g/mL at 25 °C (lit.)
• functional group: bromo
• SMILES string: Brc1cnc2ccccc2c1
• InChI: 1S/C9H6BrN/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H
• InChI key: ZGIKWINFUGEQEO-UHFFFAOYSA-N

Description

General description

3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319
• Precautionary Statements: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 230.0 °F - closed cup
• Flash Point(C): 110 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves